Supercritical CO2:: an effective medium for the chemo-enzymatic synthesis of block copolymers?

被引：25
|
作者：
Villarroya, Silvia
Thurecht, Kristofer J.
Heise, Andreas
Howdle, Steven M.
机构：
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[2] DSM Res & Patents, NL-6160 MD Geleen, Netherlands
来源：
CHEMICAL COMMUNICATIONS | 2007年 / 37期
关键词：
D O I：
10.1039/b701128h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this review, we describe the combination of enzymatic polymerisation and controlled free radical polymerisation in supercritical carbon dioxide. This combination facilitates the preparation of a range of block and graft copolymers, some of which cannot easily be obtained by conventional polymer synthesis. Biocatalysis in polymer science provides significant new opportunities and will open up a very broad range of new polymeric materials.
引用
收藏
页码：3805 / 3813
页数：9
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