Determination of Trace Copper in Water Samples by Anodic Stripping Voltammetry at Gold Microelectrode

被引：0
|
作者：
Zhuang, Jianmei [1 ]
Zhang, Li [2 ,3 ,4 ]
Lu, Wenjing [2 ,3 ,4 ]
Shen, Dazhong [1 ]
Zhu, Rilong [5 ]
Pan, Dawei [2 ,3 ]
机构：
[1] Shangdong Normal Univ, Key Lab Mol & Nanomat Probes, Minist Educ China, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Peoples R China
[2] Chinese Acad Sci, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China
[3] Chinese Acad Sci, CAS, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China
[4] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[5] Hunan Prov Environm Monitoring Ctr, Changsha 410014, Hunan, Peoples R China
来源：
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2011年 / 6卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Gold microelectrode; Copper; Anodic stripping voltammetry; Water samples; CARBON ELECTRODES; NATURAL-WATERS; SILICA; ELECTROCHEMISTRY; PRECONCENTRATION; ARRAYS; METALS; CU(II); IONS; ACID;
D O I：
暂无
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The applicability of gold microelectrode of 25 mu m diameter for electrochemical determination of trace copper ions (Cu2+) in water samples by anodic stripping voltammetry (ASV) has been demonstrated. The analysis of Cu2+ at gold microelectrode includes two steps. Cu2+ ions are firstly reduced and accumulated on the microelectrode surface during an accumulation step, then oxidized during the positive potential sweep. Due to the rapid mass transporting and low background current of gold microelectrode, low detection limit (0.3 nM) and wide linear range (1.0-90 nM) can be obtained. The practical application of gold microelectrode was verified by determination of trace level of Cu2+ in tap water, lake water and commercial drinking water samples.
引用
收藏
页码：4690 / 4699
页数：10
相关论文
共 50 条
  • [21] Simultaneous determination of trace amounts of zinc, lead and copper in rum by anodic stripping voltammetry
    Barbeira, PJS
    Stradiotto, NR
    TALANTA, 1997, 44 (02) : 185 - 188
  • [22] Electrodeposition of zinc hydroxide on carbon graphite electrode for electrochemical determination of trace copper in water samples using square wave anodic stripping voltammetry
    Berrabah, Salah Eddine
    Benchettara, Abdelkader
    Smaili, Fatiha
    Tabti, Sabrina
    Benchettara, Abdelhakim
    MATERIALS CHEMISTRY AND PHYSICS, 2022, 278
  • [23] DETERMINATION OF COPPER IN SEAWATER BY ANODIC-STRIPPING VOLTAMMETRY
    FLORENCE, TM
    BATLEY, GE
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1977, 75 (02): : 791 - 798
  • [24] Determination of Copper and Lead in Water Samples from Zamfara State, Nigeria by Linear Sweep Anodic Stripping Voltammetry
    Okiei, W.
    Ogunlesi, M.
    Adio-Adepoju, A.
    Oluboyo, M.
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2016, 11 (10): : 8280 - 8294
  • [25] Trace Determination of Lead in Environmental and Biological Samples by Anodic Stripping Voltammetry on Carbon Paste Electrode
    Rievaj, Miroslav
    Tomcik, Peter
    Cernanska, Monika
    Janosikova, Zuzana
    Bustin, Dusan
    CHEMIA ANALITYCZNA, 2008, 53 (05): : 717 - 723
  • [26] Indirect determination of sulfide ions in water samples at trace level by anodic stripping voltammetry using mercury film electrode
    Huang, Deqian
    Xu, Bolei
    Tang, Jie
    Luo, Jian
    Chen, Luhong
    Yang, Lili
    Yang, Zhengbiao
    Bi, Shuping
    ANALYTICAL METHODS, 2010, 2 (02) : 154 - 158
  • [27] APPLICATION OF ANODIC-STRIPPING VOLTAMMETRY TO DETERMINATION OF SOME TRACE ELEMENTS IN SEA WATER
    WHITNACK, GC
    SASSELLI, R
    ANALYTICA CHIMICA ACTA, 1969, 47 (02) : 267 - &
  • [28] Determination of ethylenethiourea (ETU) at trace levels in water samples by cathodic stripping voltammetry
    de Carvalho, LM
    do Nascimento, PC
    Bohrer, D
    Del-Fabro, L
    ELECTROANALYSIS, 2004, 16 (18) : 1508 - 1513
  • [29] Determination of trace amounts of copper in tap water samples with a calix[4]arene modified carbon paste electrode by differential pulse anodic stripping voltammetry
    Canpolat, Esra Celik
    Sar, Erdem
    Coskun, Naciye Yilmaz
    Cankurtaran, Husnu
    ELECTROANALYSIS, 2007, 19 (10) : 1109 - 1115
  • [30] Determination of trace amounts of copper in iron and steel by anodic stripping voltammetry after extraction of the matrix
    Tanaka, T
    Ishii, M
    BUNSEKI KAGAKU, 2001, 50 (08) : 559 - 562
12345