Facile Synthesis of π-Conjugated Quinazoline-Substituted Ethenes from 2-Ethynylanilines and Benzonitriles under Transition-Metal-Free Conditions

被引：14

作者：

Wang, Xu ^{[2
]}

Li, Jiawei ^{[2
]}

Huang, Yubing ^{[2
]}

Zhu, Jiayi ^{[2
]}

Hu, Rongrong ^{[1
]}

Wu, Wanqing ^{[1
,2
]}

Jiang, Huanfeng ^{[2
]}

机构：

[1] South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China

[2] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 83卷 / 17期

基金：

中国国家自然科学基金;

关键词：

AGGREGATION-INDUCED EMISSION; CROSS-COUPLING REACTIONS; ONE-POT SYNTHESIS; C-H ARYLATION; ROOM-TEMPERATURE; DOMINO REACTION; BENZOIC-ACIDS; DIRECT ACCESS; ACTIVATION; ALKYNYLATION;

D O I：

10.1021/acs.joc.8b01494

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new transition-metal-free version for the synthesis of ir-conjugated quinazoline-substituted ethene derivatives from readily available starting materials has been developed. Quinazoline-substituted ethenes were obtained in moderate to high yields with completely Z-selectivity, and the resulting quinazoline-substituted ethenes show typical aggregation-induced emission (AIE) properties.

引用

页码：10453 / 10464

页数：12

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