Facile Synthesis of π-Conjugated Quinazoline-Substituted Ethenes from 2-Ethynylanilines and Benzonitriles under Transition-Metal-Free Conditions

被引：14
|
作者：
Wang, Xu [2 ]
Li, Jiawei [2 ]
Huang, Yubing [2 ]
Zhu, Jiayi [2 ]
Hu, Rongrong [1 ]
Wu, Wanqing [1 ,2 ]
Jiang, Huanfeng [2 ]
机构：
[1] South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
[2] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 83卷 / 17期
基金：
中国国家自然科学基金;
关键词：
AGGREGATION-INDUCED EMISSION; CROSS-COUPLING REACTIONS; ONE-POT SYNTHESIS; C-H ARYLATION; ROOM-TEMPERATURE; DOMINO REACTION; BENZOIC-ACIDS; DIRECT ACCESS; ACTIVATION; ALKYNYLATION;
D O I：
10.1021/acs.joc.8b01494
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new transition-metal-free version for the synthesis of ir-conjugated quinazoline-substituted ethene derivatives from readily available starting materials has been developed. Quinazoline-substituted ethenes were obtained in moderate to high yields with completely Z-selectivity, and the resulting quinazoline-substituted ethenes show typical aggregation-induced emission (AIE) properties.
引用
收藏
页码：10453 / 10464
页数：12
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