The perfluorinated alcohols c-C6F11OH, c-C6F10-1,1-(OH)2 and c-C6F10-1-(CF3)OH

被引：4
|
作者：
Schaab, Jonas [1 ,2 ]
Schwab, Miriam [1 ,2 ]
Kratzert, Daniel [1 ,2 ]
Schwabedissen, Jan [3 ]
Stammler, Hans-Georg [3 ]
Mitzel, Norbert W. [3 ]
Krossing, Ingo [1 ,2 ]
机构：
[1] Albert Ludwigs Univ Freiburg, Inst Anorgan & Analyt Chem, Albertstr 21, D-79104 Freiburg, Germany
[2] FMF, Albertstr 21, D-79104 Freiburg, Germany
[3] Univ Bielefeld, Lehrstuhl Anorgan & Strukturchem, CM2, Univ Str 25, D-33615 Bielefeld, Germany
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 67期
关键词：
WEAKLY COORDINATING ANIONS; GAS ELECTRON-DIFFRACTION; COMPLEX; PHASE; TRIFLUOROMETHANOL;
D O I：
10.1039/c8cc05148h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The thermally unstable alpha-fluoroalcohol undecafluorocyclohexanol (c-C6F11OH) was prepared by addition of hydrogen fluoride to the corresponding ketone. c-C6F10(CF3) OH was obtained by protonation of its alkoxide [NMe4](+)[C7F13O](-). Decafluorocyclohexane-1,1-diol (c-C6F10(OH)(2)) was prepared by acidic workup of the corresponding alkoxide [NMe4](+)[C6F11O](-) with sulfuric acid, which yielded (c-C6F10(OH)(2)) and fluorosulfonic acid. The structures of c-C6F10(CF3)OH center dot 2H(2)O and of (c-C6F10(OH)(2)) were elucidated by single-crystal X-ray and gas-phase electron-diffraction studies.
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页码：9294 / 9297
页数：4
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