The perfluorinated alcohols c-C6F11OH, c-C6F10-1,1-(OH)2 and c-C6F10-1-(CF3)OH

被引：4

作者：

Schaab, Jonas ^{[1
,2
]}

Schwab, Miriam ^{[1
,2
]}

Kratzert, Daniel ^{[1
,2
]}

Schwabedissen, Jan ^{[3
]}

Stammler, Hans-Georg ^{[3
]}

Mitzel, Norbert W. ^{[3
]}

Krossing, Ingo ^{[1
,2
]}

机构：

[1] Albert Ludwigs Univ Freiburg, Inst Anorgan & Analyt Chem, Albertstr 21, D-79104 Freiburg, Germany

[2] FMF, Albertstr 21, D-79104 Freiburg, Germany

[3] Univ Bielefeld, Lehrstuhl Anorgan & Strukturchem, CM2, Univ Str 25, D-33615 Bielefeld, Germany

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 67期

关键词：

WEAKLY COORDINATING ANIONS; GAS ELECTRON-DIFFRACTION; COMPLEX; PHASE; TRIFLUOROMETHANOL;

D O I：

10.1039/c8cc05148h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thermally unstable alpha-fluoroalcohol undecafluorocyclohexanol (c-C6F11OH) was prepared by addition of hydrogen fluoride to the corresponding ketone. c-C6F10(CF3) OH was obtained by protonation of its alkoxide [NMe4](+)[C7F13O](-). Decafluorocyclohexane-1,1-diol (c-C6F10(OH)(2)) was prepared by acidic workup of the corresponding alkoxide [NMe4](+)[C6F11O](-) with sulfuric acid, which yielded (c-C6F10(OH)(2)) and fluorosulfonic acid. The structures of c-C6F10(CF3)OH center dot 2H(2)O and of (c-C6F10(OH)(2)) were elucidated by single-crystal X-ray and gas-phase electron-diffraction studies.

引用

页码：9294 / 9297

页数：4

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