Detection of the enantiomers of P-stereogenic pentacoordinated phosphorus compounds:: 31P NMR of oxaphosphetes in optically active solvents

被引：2
|
作者：
Kollár, L
Berente, Z
Forintos, H
Keglevich, G
机构：
[1] Univ Pecs, Dept Inorgan Chem, H-7624 Pecs, Hungary
[2] Hungarian Acad Sci, Res Grp Chem Sensors, H-7624 Pecs, Hungary
[3] Univ Pecs, Dept Biochem, H-7624 Pecs, Hungary
[4] Budapest Univ Technol & Econ, Dept Organ Chem Technol, H-1521 Budapest, Hungary
来源：
TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 22期
基金：
匈牙利科学研究基金会;
关键词：
D O I：
10.1016/S0957-4166(00)00426-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The enantiomers of spirocyclic oxaphosphetes possessing the sterically bulky 2,4,6-triisopropyl-phenyl group bound to the pentacoordinated phosphorus stereogenic centre could be distinguished in optically active amines as solvents. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：4433 / 4436
页数：4
相关论文
共 50 条
  • [41] Determination of 31P,31P coupling constants in cyclotriphosphazenes and their influence on 1H and 13C NMR spectra of phosphorus substituents
    Vicente, V
    Fruchier, A
    Cristau, HJ
    MAGNETIC RESONANCE IN CHEMISTRY, 2003, 41 (03) : 183 - 192
  • [42] 31P NMR studies on the ligand dissociation of trinuclear molybdenum cluster compounds
    Li, ZJ
    Qin, YY
    Tang, YH
    Kang, Y
    Xia, JB
    Chen, Z
    Wu, L
    Yao, YG
    CHINESE JOURNAL OF CHEMISTRY, 2003, 21 (09) : 1174 - 1177
  • [43] 31P NMR Studies on the Ligand Dissociation of Trinuclear Molybdenum Cluster Compounds
    李兆基
    覃业燕
    唐艳红
    康遥
    夏继波
    陈忠
    吴棱
    姚元根
    ChineseJournalofChemistry, 2003, (09) : 1174 - 1177
  • [44] Plasticity of the tryptophan synthase active site probed by 31P NMR spectroscopy
    J Biol Chem, 50 (33247):
  • [45] PENTACOORDINATED PHOSPHORUS AS THE INTERNUCLEOSIDE LINKAGE - SYNTHESIS AND P-31 NMR-STUDY OF THE PSEUDOROTATIONAL DYNAMICS
    KOOLE, LH
    MOODY, HM
    BUCK, HM
    RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1986, 105 (06): : 196 - 197
  • [46] Optically-detected NMR of optically-hyperpolarized 31P neutral donors in 28Si
    Steger, M.
    Sekiguchi, T.
    Yang, A.
    Saeedi, K.
    Hayden, M. E.
    Thewalt, M. L. W.
    Itoh, K. M.
    Riemann, H.
    Abrosimov, N. V.
    Becker, P.
    Pohl, H. -J.
    JOURNAL OF APPLIED PHYSICS, 2011, 109 (10)
  • [47] Forms of organic phosphorus in zonal steppe soils of Russia assessed by 31P NMR
    Amelung, W
    Rodionov, A
    Urusevskaja, IS
    Haumaier, L
    Zech, W
    GEODERMA, 2001, 103 (3-4) : 335 - 350
  • [48] Novel Approaches for Identifying Phosphorus Species in Terrestrial and Aquatic Ecosystems with 31P NMR
    Vestergren, Johan E.
    Vincent, Andrea G.
    Persson, Per
    Jansson, Mats
    Ilstedt, Ulrik
    Giesler, Reiner
    Schleucher, Jurgen
    Grobner, Gerhard
    BIOPHYSICAL JOURNAL, 2013, 104 (02) : 501A - 502A
  • [49] Monitoring of the insecticide trichlorfon by phosphorus-31 nuclear magnetic resonance (31P NMR) spectroscopy
    Talebpour, Zahra
    Ghassempour, Alireza
    Zendehzaban, Mehdi
    Bijanzadeh, Hamid Reza
    Mirjalili, Mohammad Hossein
    ANALYTICA CHIMICA ACTA, 2006, 576 (02) : 290 - 296
  • [50] Electronic properties of furyl substituents at phosphorus and their influence on 31P NMR chemical shifts
    Ackermann, Marco
    Pascariu, Aurelia
    Hoecher, Thomas
    Siehl, Hans-Ullrich
    Berger, Stefan
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (26) : 8434 - 8440
12345