Detection of the enantiomers of P-stereogenic pentacoordinated phosphorus compounds:: 31P NMR of oxaphosphetes in optically active solvents

被引:2
|
作者
Kollár, L
Berente, Z
Forintos, H
Keglevich, G
机构
[1] Univ Pecs, Dept Inorgan Chem, H-7624 Pecs, Hungary
[2] Hungarian Acad Sci, Res Grp Chem Sensors, H-7624 Pecs, Hungary
[3] Univ Pecs, Dept Biochem, H-7624 Pecs, Hungary
[4] Budapest Univ Technol & Econ, Dept Organ Chem Technol, H-1521 Budapest, Hungary
基金
匈牙利科学研究基金会;
关键词
D O I
10.1016/S0957-4166(00)00426-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The enantiomers of spirocyclic oxaphosphetes possessing the sterically bulky 2,4,6-triisopropyl-phenyl group bound to the pentacoordinated phosphorus stereogenic centre could be distinguished in optically active amines as solvents. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:4433 / 4436
页数:4
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