Iron-Catalyzed Carbonylation-Peroxidation of Alkenes with Aldehydes and Hydroperoxides

被引：288

作者：

Liu, Weiping ^{[1
]}

Li, Yuanming ^{[1
]}

Liu, Kaisheng ^{[1
]}

Li, Zhiping ^{[1
]}

机构：

[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 28期

基金：

美国国家科学基金会;

关键词：

C-C BOND; RADICAL CHEMISTRY; EPOXIDATION; OXIDATION; CARBON; FUNCTIONALIZATION; HYDROACYLATION; ACTIVATION; ESTERS; SCOPE;

D O I：

10.1021/ja204226n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A three-component reaction of alkenes, aldehydes, and hydroperoxides catalyzed by FeCl2 to beta-peroxy ketones has been achieved. This three-component reaction can be also applied to the synthesis of a-carbonyl epoxides, through either a stepwise base-induced epoxidation of the separated beta-peroxy ketone products or a one-pot process by simply adding base to the reaction mixture after the completion of the three-component reaction.

引用

页码：10756 / 10759

页数：4

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