Structural and impedance studies of praseodymium based orthoferrites for solid oxide fuel cells

被引:0
|
作者
SrinivasReddy, Padigela [1 ,2 ]
Konagolla, Saibaba [3 ]
Vaidya, Prashanth Kumar [4 ]
Sripada, Suresh [5 ]
机构
[1] JNTU, Dept Phys, Hyderabad 500085, Telangana, India
[2] Malla Reddy Univ, Dept Phys, Hyderabad 500043, Telangana, India
[3] Inst Aeronaut Engn, Dept Phys, Hyderabad 500043, Telangana, India
[4] Kakatiya Inst Technol & Sci, Dept Phys Sci, Warangal 506015, Andhra Pradesh, India
[5] JNTUH CEJ, Dept Phys, Kodimial M 505501, TS, India
关键词
Perovskites; Sol -gel route; Crystalline structure; DIELECTRIC-CONSTANT; ELECTRICAL-PROPERTIES;
D O I
10.1016/j.matpr.2022.04.466
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Impedance analysis was applied to perovskite oxides of Pr(0.8)Sr(0.2)Fe(1-x)CoxO(3) (x = 0 and 1) materials. The single-phase perovskite-based rare earth orthoferrites are made using the sol-gel route. The present sampled are made from a single-phase solid solution of orthorhombic perovskite composition. Structural properties of the indefinite perovskite Pr0.8Sr0.2Fe1-xCoxO3 phase are confirmed by powder XRD. At room temperature, XRD is utilized to resolve the lattice properties (almost 27-30 degrees C). Conductive behavior of the perovskite is discussed with respect to the temperature to frequency and impedance. The impedance decrement shows evidence of the conductivity of the samples. The volume and lattice properties of Fe and Co material increase as these are growing. The diffraction records for highly condensed samples revealed no evidence of Samarium and Strontium order at the A site, nor of oxygen situation ordering at the O sites. Copyright (C) 2022 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the International Conference on Advanced Materials for Innovation and Sustainability.
引用
收藏
页码:246 / 249
页数:4
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