Interactions of lignin and LDPE during catalytic co-pyrolysis: Thermal behavior and kinetics study by TG-FTIR

被引:34
|
作者
Tao, Liangliang [1 ]
Ma, Xianming [1 ]
Ye, Lihui [1 ]
Jia, Jingwen [1 ]
Wang, Lu [1 ]
Ma, Peiyong [2 ]
Liu, Jian [1 ,3 ]
机构
[1] Hefei Univ Technol, Sch Food & Biol Engn, Hefei 230009, Anhui, Peoples R China
[2] Hefei Univ Technol, Sch Mech Engn, Hefei 230009, Anhui, Peoples R China
[3] Hefei Univ Technol, Minist Educ, Engn Res Ctr Bioproc, Hefei 230009, Peoples R China
关键词
Lignin; LDPE; Catalytic co-pyrolysis; TG-FTIR; Synergistic effect; DENSITY POLYETHYLENE; RICE STRAW; PLASTICS; BIOMASS; WASTE; BLENDS; DEGRADATION; HYDROGEN; FUELS;
D O I
10.1016/j.jaap.2021.105267
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Thermal behavior and interaction of Low-density polyethylene (LDPE) and lignin with HZSM-5 as catalyst during catalytic co-pyrolysis were analyzed by thermogravimetric analyzer coupled with Fourier transform infrared spectrometer (TG-FTIR). The synergistic effect of lignin and hydrogen-rich LDPE decreased the starting temperature of pyrolysis and accelerated the pyrolysis rate. Kinetic analysis based on the Coats-Redfern method showed that HZSM-5 catalysis significantly decreased the reaction's activation energy. FTIR results also indicated that the composition of pyrolysis products shifted to more alkane and aromatics by co-feeding the lignin with LDPE and catalyst HZSM-5.
引用
收藏
页数:5
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