Endosulfan Elimination Using Amine-Modified Magnetic Diatomite as an Adsorbent

被引:8
|
作者
Alacabey, Ihsan [1 ]
机构
[1] Mardin Artuklu Univ, Vocat Higher Sch Healthcare Studies, Mardin, Turkey
来源
FRONTIERS IN CHEMISTRY | 2022年 / 10卷
关键词
adsorption isotherms; endosulfan; magnetic diatomite; pesticide; silane; SOLUTE ADSORPTION-ISOTHERM; AQUEOUS-SOLUTION; PESTICIDE REMOVAL; GENERAL TREATMENT; WATER; IONS; CLASSIFICATION; MICROPARTICLES; EQUILIBRIUM; VEGETABLES;
D O I
10.3389/fchem.2022.907302
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pesticides are among the most dangerous developing toxins since they are very hazardous to the environment and threaten human health. In this study, researchers successfully manufactured surface-modified magnetic diatomite (m-DE-APTES) and used them as a sorbent to extract endosulfan from an aqueous solution. There is no other study like it in the scholarly literature, and the results are astounding. Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), electron spin resonance (ESR), and surface area measurements were used to analyze magnetic diatomite particles with surface modification. According to the analysis results, magnetic diatomite has a wide surface area and a porous structure. Furthermore, m-DE-APTES has a higher endosulfan adsorption capacity (97.2 mg g(-1)) than raw diatomite (DE) (16.6 mg g(-1)). Adsorption statistics agree with Langmuir adsorption isotherm (R-2 = 0.9905), and the adsorption occurred spontaneously at -2.576 kj mol(-1) in terms of Delta G(o). Finally, m-DE-APTES are a viable alternative adsorbent for removing pesticides from aqueous solutions.
引用
收藏
页数:11
相关论文
共 50 条
  • [31] Synthesis and characterization of amine-modified spherical nanocellulose aerogels
    Wang, Xiaoyu
    Zhang, Yang
    Wang, Siqun
    Jiang, Hua
    Liu, Shuang
    Yao, Yuan
    Zhang, Tianmeng
    Li, Qian
    JOURNAL OF MATERIALS SCIENCE, 2018, 53 (18) : 13304 - 13315
  • [32] Amine-modified silica for removing aspirin from water
    A. F. Danil de Namor
    M. Al Nuaim
    G. Fairclough
    R. Khalife
    N. Al Hakawati
    International Journal of Environmental Science and Technology, 2022, 19 : 4143 - 4152
  • [33] Green Synthesis and Characterization of Amine-Modified Starch Nanoparticles
    Suhai, Awangku Abdullah Kamarol Awg
    Chin, Suk-Fun
    STARCH-STARKE, 2021, 73 (1-2):
  • [34] Preparation of amine-modified lignin adsorbent for highly efficient and selective removal of sodium dodecyl benzene sulfonate from greywater
    Dai, Chang
    Li, Yun
    Qi, Benkun
    Li, Zhitao
    He, Zhiqin
    Wang, Bin
    Fang, Fei
    Dai, Xuhuan
    Qin, Xiaopeng
    Wan, Yinhua
    SEPARATION AND PURIFICATION TECHNOLOGY, 2025, 353
  • [35] Enhanced photocatalytic degradation of psychoactive substances using amine-modified elongated titanate nanostructures
    Barrocas, B.
    Neves, M. C.
    Conceicao Oliveira, M.
    Monteiro, O. C.
    ENVIRONMENTAL SCIENCE-NANO, 2018, 5 (02) : 350 - 361
  • [36] Study on the preparation of amine-modified silicate MCM-41 adsorbent and its H2S removal performance
    Zhang, Jiaojing
    Song, Hua
    Chen, Yanguang
    Hao, Tianzhen
    Li, Feng
    Yuan, Dandan
    Wang, Xueqin
    Zhao, Liang
    Gao, Jinsen
    PROGRESS IN REACTION KINETICS AND MECHANISM, 2019, 45
  • [37] Electrostatic dissipating properties of poly(oxyethylene)amine-modified polyamides
    Young, Mang-Yao
    Lin, Jiang-Jen
    Industrial and Engineering Chemistry Research, 1998, 37 (11): : 4284 - 4289
  • [38] CO2 adsorption on amine-modified mesoporous silicas
    Juanjuan Ma
    Qiming Liu
    Dandan Chen
    Sheng Wen
    Tianhe Wang
    Journal of Porous Materials, 2014, 21 : 859 - 867
  • [39] Amine-modified random primers to label probes for DNA microarrays
    Charlie C. Xiang
    Olga A. Kozhich
    Mei Chen
    Jason M. Inman
    Quang N. Phan
    Yidong Chen
    Michael J. Brownstein
    Nature Biotechnology, 2002, 20 (7) : 738 - 742
  • [40] Amine-modified nucleosides as adenosine A3 neoceptor ligands
    Van Rompaey, P
    Jacobson, KA
    Gao, ZG
    Chen, A
    Barak, D
    Kim, SA
    Lee, K
    Link, A
    Liang, BT
    Herdewijn, P
    Van Calenbergh, S
    CHEMISTRY OF NUCLEIC ACID COMPONENTS, 2002, 5 : 267 - 271