Endosulfan Elimination Using Amine-Modified Magnetic Diatomite as an Adsorbent

被引:8
|
作者
Alacabey, Ihsan [1 ]
机构
[1] Mardin Artuklu Univ, Vocat Higher Sch Healthcare Studies, Mardin, Turkey
来源
FRONTIERS IN CHEMISTRY | 2022年 / 10卷
关键词
adsorption isotherms; endosulfan; magnetic diatomite; pesticide; silane; SOLUTE ADSORPTION-ISOTHERM; AQUEOUS-SOLUTION; PESTICIDE REMOVAL; GENERAL TREATMENT; WATER; IONS; CLASSIFICATION; MICROPARTICLES; EQUILIBRIUM; VEGETABLES;
D O I
10.3389/fchem.2022.907302
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pesticides are among the most dangerous developing toxins since they are very hazardous to the environment and threaten human health. In this study, researchers successfully manufactured surface-modified magnetic diatomite (m-DE-APTES) and used them as a sorbent to extract endosulfan from an aqueous solution. There is no other study like it in the scholarly literature, and the results are astounding. Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), electron spin resonance (ESR), and surface area measurements were used to analyze magnetic diatomite particles with surface modification. According to the analysis results, magnetic diatomite has a wide surface area and a porous structure. Furthermore, m-DE-APTES has a higher endosulfan adsorption capacity (97.2 mg g(-1)) than raw diatomite (DE) (16.6 mg g(-1)). Adsorption statistics agree with Langmuir adsorption isotherm (R-2 = 0.9905), and the adsorption occurred spontaneously at -2.576 kj mol(-1) in terms of Delta G(o). Finally, m-DE-APTES are a viable alternative adsorbent for removing pesticides from aqueous solutions.
引用
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页数:11
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