Stereoselective synthesis of (3E)-2-stannyl-1,3-dienes via palladium catalysed cross-coupling reactions

被引：0

作者：

Cai, MZ ^{[1
]}

Li, HG ^{[1
]}

Hao, WY ^{[1
]}

机构：

[1] Jiangxi Normal Univ, Dept Chem, Nanchang 330027, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 2005年 / 02期

关键词：

palladium; zirconium; tin; 1,3-diene; cross-coupling reaction;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrozirconation of terminal alkynes 1 gives (E)-alkenylzirconium complexes 3, which when cross-coupled with α-iodoethenylstannanes 4 in the presence of [Pd(PPh3)(4)] catalyst afford stereciselectively (3E)-2-stannyl-1,3-dienes 5 in good yields.

引用

页码：103 / 104

页数：2

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