Stereoselective synthesis of (3E)-2-stannyl-1,3-dienes via palladium catalysed cross-coupling reactions

被引：0

作者：

Cai, MZ ^{[1
]}

Li, HG ^{[1
]}

Hao, WY ^{[1
]}

机构：

[1] Jiangxi Normal Univ, Dept Chem, Nanchang 330027, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 2005年 / 02期

关键词：

palladium; zirconium; tin; 1,3-diene; cross-coupling reaction;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrozirconation of terminal alkynes 1 gives (E)-alkenylzirconium complexes 3, which when cross-coupled with α-iodoethenylstannanes 4 in the presence of [Pd(PPh3)(4)] catalyst afford stereciselectively (3E)-2-stannyl-1,3-dienes 5 in good yields.

引用

页码：103 / 104

页数：2

共 50 条

[31] Stereoselective synthesis of (E,E)-1-arylselenobutadienes by cross-coupling reactions in the presence of palladium catalyst
Zhu, LS
Huang, ZZ
Huang, X
TETRAHEDRON, 1996, 52 (29) : 9819 - 9822
[32] STEREOSELECTIVE SYNTHESIS OF (3E,5E)-DIEN-2-ONES AND (2E,4E)-DIENALS VIA 2-PHENYLSULFONYL 1,3-DIENES
BACKVALL, JE
ERICSSON, AM
PLOBECK, NA
JUNTUNEN, SK
TETRAHEDRON LETTERS, 1992, 33 (01) : 131 - 134
[33] METHYLCOPPER INDUCED COUPLING OF DIALKENYLCHLOROBORANES - NEW PROCEDURE FOR STEREOSELECTIVE SYNTHESIS OF (E,E)-1,3-DIENES
YAMAMOTO, Y
YATAGAI, H
MORITANI, I
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (19) : 5606 - 5607
[34] Regiospecific synthesis of symmetrical (1E,3E) 2,3-diphenyl-1,4diphenyl-buta-1,3-dienes via palladium-catalyzed cross-coupling of (Z) 2-bromo-2-fluoroethenylbenzenes in presence of bis(pinacolato)diboron
Eddarir, S
Rolando, C
JOURNAL OF FLUORINE CHEMISTRY, 2004, 125 (03) : 377 - 380
[35] Stereoselective Synthesis of Trisubstituted (E,E)-1,3-Dienes by the Site-Selective Reductive Cross-Coupling of Internal Alkynes with Terminal Alkynes: A Fragment Coupling Reaction for Natural Product Synthesis
Perez, Lark J.
Shimp, Heidi L.
Micalizio, Glenn C.
JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (19): : 7211 - 7219
[36] Preparation of 2-Silicon-Substituted 1,3-Dienes and Their Diels-Alder/Cross-Coupling Reactions
Pidaparthi, Ramakrishna R.
Junker, Christopher S.
Welker, Mark E.
Day, Cynthia S.
Wright, Marcus W.
JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (21): : 8290 - 8297
[37] Preparation of 2-trialkylsiloxy-substituted 1,3-dienes and their Diels-Alder/cross-coupling reactions
Pidaparthi, Ramakrishna R.
Welker, Mark E.
Day, Cynthia S.
Wright, Marcus W.
ORGANIC LETTERS, 2007, 9 (09) : 1623 - 1626
[38] The stereoselective preparation of fluorinated dienes via Stille-Liebeskind cross-coupling reactions
Zhang, X
Lu, L
Burton, DJ
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2002, 67 (09) : 1247 - 1261
[39] Synthesis of (1E,3E)-1,4-diarylbuta-1,3-dienes promoted by μ-OMs palladium–dimer complex
Xueliang Zhou
Yuan Zhou
Qiang Zhu
Huimin Chen
Nan Wu
Xiangru Wen
Zhou Xu
BMC Chemistry, 13
[40] Highly efficient synthesis of 1,1-difluoro-2-substituted-1,3-dienes and dienynes from gem-difluorohomoallenyl bromide via palladium-catalyzed cross-coupling reactions
Shen, QL
Hammond, GB
ORGANIC LETTERS, 2001, 3 (14) : 2213 - 2215

← 1 2 3 4 5 →