Reactions of R4Sb2 (R = Me, Et) with (Me3SiCH2)3M (M = Ga, In) and crystal structures of [(Me3SiCH2)2InSbMe2]3 and [(Me3SiCH2)2GaOSbEt2]2

被引：0

作者：

Breunig, HJ ^{[1
]}

Stanciu, M ^{[1
]}

Rösler, R ^{[1
]}

Lork, E ^{[1
]}

机构：

[1] Univ Bremen, Inst Anorgan & Phys Chem, D-28334 Bremen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 12期

关键词：

gallium; indium; antimony; x-ray diffraction;

D O I：

10.1002/(SICI)1521-3749(1998120)624:12<1965::AID-ZAAC1965>3.0.CO;2-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of (Me3SiCH2)(3)In with Me2SbSbMe2 gives [(Me3SiCH2)(2)InSbMe2](3) (1) and Me3SiCH2SbMe2. [(Me3SiCH2)(2)GaOSbEt2](2) (2) is formed by the reaction of (Me3SiCH2)(3)Ga with Et2SbSbEt2 and oxygen. The syntheses and the crystal structures of 1 and 2 are reported.

引用

页码：1965 / 1968

页数：4

共 50 条

[41] Organoantimony ring-chain equilibria:: Trapping of catena-tetrastibanes in cyclo-[Cr(CO)4(R′2Sb-SbR-SbR-SbR′2)] (R′ = Me, Ph; R = Me3SiCH2) and related complexes
Breunig, HJ
Ghesner, I
Lork, E
ORGANOMETALLICS, 2001, 20 (07) : 1360 - 1364
[42] Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R = Et), [(Cp2Ti)3(SbR)3Sb] [R=2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R = Me3SiCH2)
Breunig, Hans J.
Lork, Enno
Moldovan, Ovidiu
Rat, Ciprian I.
Rosenthal, Uwe
Silvestru, Cristian
DALTON TRANSACTIONS, 2009, (26) : 5065 - 5067
[43] SYNTHESIS AND CHARACTERIZATION OF (ME(3)SICH(2))(3)M-CENTER-DOT-E(SIME(3))(3) (M=GA, E=P OR AS M=IN, E=P) - X-RAY CRYSTAL-STRUCTURES OF(ME(3)SICH(2))(3)GA-CENTER-DOT-P(SIME(3))(3) AND (ME(3)SICH(2))(3)IN-CENTER-DOT-P(SIME(3))(3)
WELLS, RL
BALDWIN, RA
WHITE, PS
ORGANOMETALLICS, 1995, 14 (04) : 2123 - 2126
[44] Trimethylene-bridged tetraorganodistannoxanes {[Me3SiCH2(RCOO)Sn (CH2)3Sn(OOCR) CH2SiMe3]O}n (R = Ph, 2,4-Me2C6H3): Control of structure by variation of R
Costisella B.
Dakternieks D.
Jurkschat K.
Mehring M.
Paulus I.
Scḧrmann M.
Chemistry of Heterocyclic Compounds, 2001, Kluwer Academic/Plenum Publishers (37) : 1405 - 1417
[45] ISOLATION AND CHARACTERIZATION OF AN ORGANOGALLIUM ARSENIC CLUSTER - CRYSTAL-STRUCTURE OF [(PHASH)(ME3SICH2GA)(PNAS)6(ME3SICH2GA)4]
WELLS, RL
PURDY, AP
MCPHAIL, AT
PITT, CG
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (06) : 487 - 488
[46] Synthesis and characterization of [(Me3SiCH2)2GaP(SiMe3)2]2, an example of a gallium-phosphorus dimer obtainable only through an indirect reaction pathway
Wells, RL
Foos, EE
Baldwin, RA
Rheingold, AL
Yap, GPA
HETEROATOM CHEMISTRY, 1998, 9 (02) : 147 - 150
[47] Synthesis and characterization of an organothallium-phosphorus adduct: Crystal structure of (Me3SiCH2)(3)Tl center dot P(SiMe3)(3)
Baldwin, RA
Wells, RL
White, PS
MAIN GROUP CHEMISTRY, 1997, 2 (01) : 67 - 71
[48] Hydrolysis of Me3SiCH2 groups on a double-chelating bis(ferrocenediyl) diphosphine coordinating to a Pt(0) center
Abe, Kanako
Kubo, Kazuyuki
Kume, Shoko
Mizuta, Tsutomu
POLYHEDRON, 2016, 110 : 114 - 118
[49] 2-(TRIMETHYLSILYL)ETHYL (ME3SICH2CH2) GLYCOSIDES .10. SYNTHESIS OF 3'-DEOXYFLUOROLACTOSE AND 4'-DEOXYFLUOROLACTOSE AND ITS ME3SICH2CH2 AND CERAMIDE DERIVATIVES
EKBERG, T
MAGNUSSON, G
CARBOHYDRATE RESEARCH, 1993, 249 (01) : 117 - 125
[50] REACTIONS INVOLVING ORGANOINDIUM AND TRIMETHYLSILYL PNICTIDE COMPOUNDS - SYNTHETIC PATHWAYS TO THE NOVEL 13-15 COMPOUNDS R3M-CENTER-DOT-E(SIME3)3 (R=ME3SICH2, M=IN OR GA, E=P) AND GA[AS(SIME3)2]3
BALDWIN, RA
AUBUCHON, SR
LUBE, MS
SELF, MF
WELLS, RL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 478 - INOR

← 1 2 3 4 5 →