Reactions of R4Sb2 (R = Me, Et) with (Me3SiCH2)3M (M = Ga, In) and crystal structures of [(Me3SiCH2)2InSbMe2]3 and [(Me3SiCH2)2GaOSbEt2]2

被引:0
|
作者
Breunig, HJ [1 ]
Stanciu, M [1 ]
Rösler, R [1 ]
Lork, E [1 ]
机构
[1] Univ Bremen, Inst Anorgan & Phys Chem, D-28334 Bremen, Germany
来源
关键词
gallium; indium; antimony; x-ray diffraction;
D O I
10.1002/(SICI)1521-3749(1998120)624:12<1965::AID-ZAAC1965>3.0.CO;2-R
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of (Me3SiCH2)(3)In with Me2SbSbMe2 gives [(Me3SiCH2)(2)InSbMe2](3) (1) and Me3SiCH2SbMe2. [(Me3SiCH2)(2)GaOSbEt2](2) (2) is formed by the reaction of (Me3SiCH2)(3)Ga with Et2SbSbEt2 and oxygen. The syntheses and the crystal structures of 1 and 2 are reported.
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页码:1965 / 1968
页数:4
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