Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

被引：66

作者：

Teo, YC ^{[1
]}

Tan, KT ^{[1
]}

Loh, TP ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 10期

关键词：

D O I：

10.1039/b412736f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, alpha,beta-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities ( 90 - 96% ee).

引用

页码：1318 / 1320

页数：3

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