Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

被引：66
|
作者：
Teo, YC [1 ]
Tan, KT [1 ]
Loh, TP [1 ]
机构：
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 10期
关键词：
D O I：
10.1039/b412736f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, alpha,beta-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities ( 90 - 96% ee).
引用
收藏
页码：1318 / 1320
页数：3
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