Catalytic enantioselective allylation of ketones via a chiral indium(III) complex

被引：89
|
作者：
Teo, YC
Goh, JD
Loh, TP [1 ]
机构：
[1] Nanyang Technol Univ, Div Chem & Biol Chem, Singapore 637616, Singapore
[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
来源：
ORGANIC LETTERS | 2005年 / 7卷 / 13期
关键词：
D O I：
10.1021/ol051018n
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributylstannanes to ketones. The allylation of a variety of aromatic, alpha,beta-unsaturated and aliphatic ketones resulted in good yields and high enantioselectivities (up to 92% ee).
引用
收藏
页码：2743 / 2745
页数：3
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