Ruthenium-catalyzed 1,2,3-triazole directed intermolecular C-H amidation of arenes with sulfonyl azides

被引：26

作者：

Wang, Xiaoyu

Zhang, Chen

Li, Jue

Jiang, Chong

Su, Fu

Zhan, Zhen

Hai, Li

Chen, Zhonghua ^{[1
]}

Wu, Yong ^{[1
]}

机构：

[1] Sichuan Univ, West China Sch Pharm, Key Lab Drug Targeting, Educ Minist, Chengdu 610041, Peoples R China

来源：

RSC ADVANCES | 2016年 / 6卷 / 73期

基金：

中国国家自然科学基金;

关键词：

ROOM-TEMPERATURE; BOND ACTIVATION; 2-SUBSTITUTED 1,2,3-TRIAZOLES; PROTECTED ARYLAMINES; RECEPTOR ANTAGONIST; COUPLING REACTIONS; DIRECT ARYLATIONS; AROMATIC KETONES; CUPRIC ACETATE; ORGANIC AZIDES;

D O I：

10.1039/c6ra14020c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of 2-(2H-1,2,3-triazole-2-yl) aniline derivatives from 2-aryl-1,2,3-triazoles and sulfonylazides through ruthenium-catalyzed intermolecular C-H amidation is achieved. This reaction provides an environmentally benign protocol for C-N bond formation, producing N-2 gas as the sole byproduct. Yet a number of functionalities are well tolerated, obtaining the desired products in moderate to excellent yields.

引用

页码：68929 / 68933

页数：5

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