Heavier N-heterocyclic half-sandwich tetrylenes

被引:4
|
作者
Bischoff, Inga-Alexandra [1 ]
Morgenstern, Bernd [1 ]
Schaefer, Andre [1 ]
机构
[1] Saarland Univ, Fac Nat Sci & Technol, Dept Chem, Campus Saarbrucken, D-66123 Saarbrucken, Germany
关键词
Transition metals;
D O I
10.1039/d2cc03107h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
ansa-Half-sandwich complexes of the group 14 elements germanium, tin and lead are reported, which represent a new class of Lewis amphiphilic tetrylenes and bridge the gap between classical N-heterocyclic systems and group 14 metallocenes. These compounds can form complexes both with carbenes and transition metal fragments.
引用
收藏
页码:8934 / 8937
页数:5
相关论文
共 50 条
  • [41] Multidentate N-heterocyclic carbene ligands and heavier main group 14 element
    Youngs, WJ
    Custer, PD
    Garrison, JC
    Kofron, WJ
    Polanski, N
    Simons, RS
    Tessier, CA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U585 - U585
  • [42] N-Heterocyclic Carbene Adducts of Phenyldioxophosphorane and Its Heavier Sulfur and Selenium Analogues
    Bockfeld, Dirk
    Bannenberg, Thomas
    Jones, Peter G.
    Tamm, Matthias
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (28) : 3452 - 3458
  • [43] Synthesis and reactivity of N-heterocyclic carbene (NHC)-supported heavier nitrile ylides
    Sarkar, Debotra
    Dutta, Sayan
    Hanusch, Franziska
    Koley, Debasis
    Inoue, Shigeyoshi
    CHEMICAL SCIENCE, 2024, 15 (07) : 2391 - 2397
  • [44] Half-sandwich iridiumIII complexes with pyrazole-substituted heterocyclic frameworks and their biological applications
    Gajera, Sanjay B.
    Mehta, Jugal V.
    Thakor, Parth
    Thakkar, Vasudev R.
    Chudasama, Piyushkumar C.
    Patel, Jagdish S.
    Patel, Mohan N.
    NEW JOURNAL OF CHEMISTRY, 2016, 40 (12) : 9968 - 9980
  • [45] Unique Class of Enantiopure N-Heterocyclic Carbene Half-Sandwich Iridium(III) Complexes with Stable Configurations: Probing Five-Membered versus Six-Membered Iridacycles
    Groue, Antoine
    Tranchier, Jean-Philippe
    Rager, Marie-Noelle
    Gontard, Geoffrey
    Jean, Marion
    Vanthuyne, Nicolas
    Pearce, Harrison R.
    Cooksy, Andrew L.
    Amouri, Hani
    INORGANIC CHEMISTRY, 2019, 58 (05) : 2930 - 2933
  • [46] Half-Sandwich (η6-Benzene)Ruthenium(II) Complex of Picolyl Functionalized N-Heterocyclic Carbene as an Efficient Catalyst for Thioether Directed C-H Alkenylation of Arenes
    Kumari, Sangeeta
    Sharma, Charu
    Srivastava, Avinash K.
    Satrawala, Naveen
    Sharma, Kamal N.
    Joshi, Raj K.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2021, 2021 (35) : 3648 - 3653
  • [47] Half-sandwich and sandwich compounds of ditungsten and dimolybdenum.
    Hollandsworth, CB
    Chisholm, MH
    Gallucci, J
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U1437 - U1437
  • [48] New Sandwich and Half-Sandwich Titanium Hydrazido Compounds
    Selby, Jonathan D.
    Feliz, Marta
    Schwarz, Andrew D.
    Clot, Eric
    Mountford, Philip
    ORGANOMETALLICS, 2011, 30 (08) : 2295 - 2307
  • [49] Interactions of aromatic ligands in sandwich and half-sandwich compounds
    Malenov, D.
    Zaric, S.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2022, 78 : E201 - E201
  • [50] Half-sandwich trihydrido ruthenium complexes
    Osipov, Alexandr L.
    Gutsulyak, Dmitry V.
    Kuzmina, Lyudmila G.
    Howard, Judith A. K.
    Lemenovskii, Dmitry A.
    Suess-Fink, Georg
    Nikonov, Georgii I.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (22) : 5081 - 5085