Heavier N-heterocyclic half-sandwich tetrylenes

被引:4
|
作者
Bischoff, Inga-Alexandra [1 ]
Morgenstern, Bernd [1 ]
Schaefer, Andre [1 ]
机构
[1] Saarland Univ, Fac Nat Sci & Technol, Dept Chem, Campus Saarbrucken, D-66123 Saarbrucken, Germany
关键词
Transition metals;
D O I
10.1039/d2cc03107h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
ansa-Half-sandwich complexes of the group 14 elements germanium, tin and lead are reported, which represent a new class of Lewis amphiphilic tetrylenes and bridge the gap between classical N-heterocyclic systems and group 14 metallocenes. These compounds can form complexes both with carbenes and transition metal fragments.
引用
收藏
页码:8934 / 8937
页数:5
相关论文
共 50 条
  • [31] The Coupling of N-Heterocyclic Carbenes to Terminal Alkynes at Half Sandwich Cobalt NHC Complexes
    Lubitz, Katharina
    Radius, Udo
    ORGANOMETALLICS, 2019, 38 (12) : 2558 - 2572
  • [32] An N-Heterocyclic Carbene-Nickel Half-Sandwich Complex as a Precatalyst for Suzuki Miyaura Coupling of Aryl/Heteroaryl Halides with Aryl/Heteroarylboronic Acids
    Ando, Shin
    Matsunaga, Hirofumi
    Ishizuka, Tadao
    JOURNAL OF ORGANIC CHEMISTRY, 2017, 82 (02): : 1266 - 1272
  • [33] N-Heterocyclic Carbene Coordinated Neutral and Cationic Heavier Cyclopropylidenes
    Jana, Anukul
    Omlor, Isabell
    Huch, Volker
    Rzepa, Henry S.
    Scheschkewitz, David
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (37) : 9953 - 9956
  • [34] Half-sandwich Ru(II), Ir(III) and Rh(III) complexes with bridging or chelating N-heterocyclic bis-carbene ligand: Synthesis and characterization
    Su, Ge
    Huo, Xian-Kuan
    Jin, Guo-Xin
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (02) : 533 - 538
  • [35] Glucose oxidase mimicking half-sandwich nickel(II) complexes of coumarin substituted N-heterocyclic carbenes as novel molecular electrocatalysts for ultrasensitive and selective determination of glucose
    Brinda, K. N.
    Achar, Gautam
    Malecki, Jan Grzegorz
    Budagumpi, Srinivasa
    Nagaraju, D. H.
    Suvina, V.
    Balakrishna, R. Geetha
    BIOSENSORS & BIOELECTRONICS, 2019, 134 : 24 - 28
  • [36] Reactivity of N-Heterocyclic Carbene Half-Sandwich Ru-, Os-, Rh-, and Ir-Based Complexes with Cysteine and Selenocysteine: A Computational Study
    Tolbatov, Iogann
    Marrone, Alessandro
    INORGANIC CHEMISTRY, 2022, 61 (01) : 746 - 754
  • [37] Sandwich and half-sandwich (imido)niobium complexes
    Antiñolo, A
    Fajardo, M
    Otero, A
    Prashar, S
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (01) : 17 - 28
  • [38] HALF-SANDWICH CYCLOOCTATETRAENETHORIUM COMPOUNDS
    LEVANDA, C
    SOLAR, JP
    STREITWIESER, A
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (06) : 2128 - 2129
  • [39] Synthesis, characterization, and catalytic activity of half-sandwich ruthenium complexes with pyridine/phenylene bridged NHC = E (NHC = N-heterocyclic carbene, E = S, Se) ligands
    Jia, Wei-Guo
    Du, Teng-Teng
    Gao, Li-Li
    Du, Jun
    APPLIED ORGANOMETALLIC CHEMISTRY, 2020, 34 (07)
  • [40] Different approaches to mid-valent, paramagnetic half-sandwich complexes of the heavier group 6 metals
    Poli, R
    SYNLETT, 1999, (07) : 1019 - 1028