Iron-Catalyzed C-N Bond Formation via the Beckmann Rearrangement

被引：26
|
作者：
Jefferies, Latisha R. [1 ]
Weber, Savannah R. [1 ]
Cook, Silas P. [1 ]
机构：
[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA
来源：
SYNLETT | 2015年 / 26卷 / 03期
基金：
美国国家科学基金会;
关键词：
iron; amides; Beckmann rearrangement; oximes; lewis acid; ASYMMETRIC TOTAL-SYNTHESIS; KETOXIMES; ALCOHOLS;
D O I：
10.1055/s-0034-1379540
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple, iron-based catalytic system allows for facile Beckmann rearrangement of various oximes' The mild conditions avoid the Use of harsh or expensive acids, and the reactions do not require an inert atmosphere. Additionally, a range of amides can be accessed through this transformation.
引用
收藏
页码：331 / 334
页数：4
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