Effect of temperature on the corrosion of Cu-Pd hydrogen separation membrane alloys in simulated syngas containing H2S

被引：8
|
作者：
Nielsen, Benjamin C. [1 ,2 ]
Dogan, Omer N. [1 ]
Howard, Bret H. [3 ]
机构：
[1] US DOE, Natl Energy Technol Lab, Albany, OR 97321 USA
[2] URS Corp, Albany, OR 97321 USA
[3] US DOE, Natl Energy Technol Lab, Pittsburgh, PA 15236 USA
来源：
CORROSION SCIENCE | 2015年 / 96卷
关键词：
Alloy; Copper; SEM; XRD; High temperature corrosion; Sulfidation; SURFACE SEGREGATION; SULFIDE; PERMEANCE;
D O I：
10.1016/j.corsci.2015.03.017
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The resistance to sulfidation of hydrogen separation membranes was examined by exposing Pd, Cu, and four Cu-Pd alloys to simulated syngas containing H2S at four different temperatures. The mass change of the samples was determined and the exposed surfaces were characterized by SEM/EDS and XRD. The binary alloys showed much better corrosion resistance than the pure metals at all temperatures. The binary alloys showed a trend reversal, with the high Pd alloys gaining the most mass at the lower temperatures due to sulfidation, while the high Cu alloys gained the most mass at the higher temperatures due to oxidation. Published by Elsevier Ltd.
引用
收藏
页码：74 / 86
页数：13
相关论文
共 50 条
  • [41] Effect of support and reduction temperature in the hydrogenation of CO2 over the Cu-Pd bimetallic catalyst with high Cu/Pd ratio
    Xu, Yamei
    Ding, Ziluo
    Qiu, Rui
    Hou, Ruijun
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (65) : 27973 - 27985
  • [42] Effect of H2S on corrosion in polluted waters:: a review
    Wiener, M. S.
    Salas, B. V.
    Quintero-Nunez, M.
    Zlatev, R.
    CORROSION ENGINEERING SCIENCE AND TECHNOLOGY, 2006, 41 (03) : 221 - 227
  • [43] Effect of H2S concentration and temperature on the corrosion behavior of carbon steel in NACE solution
    Liu, Wen-Hui
    Dong, Yu
    Liu, Jian-Hua
    Wu, Hao
    Yu, Mei
    Liu, Wen-Hui
    Beijing Keji Daxue Xuebao/Journal of University of Science and Technology Beijing, 2012, 34 (10): : 1152 - 1158
  • [44] Effect of Cl~- on electrochemical corrosion behavior of H2S
    LIU Mingliang
    ZHOU Qingjun
    QI Qingju
    Baosteel Technical Research, 2019, 13 (03) : 27 - 34
  • [45] CORROSION OF FECRAL, FECRALY, AND FECRALHF ALLOYS IN HIGH-TEMPERATURE H2/H2O/H2S ENVIRONMENTS
    HUANG, TT
    LIN, YC
    ZHANG, YH
    SHORES, DA
    PFENDER, E
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1983, 130 (08) : C335 - C335
  • [46] Effect of Temperature on the Corrosion Behaviours of L360QCS in the Environments Containing Elemental Sulphur and H2S/CO2
    Zheng, Shuqi
    Li, Chunyu
    Chen, Changfeng
    METALLOFIZIKA I NOVEISHIE TEKHNOLOGII, 2012, 34 (01): : 57 - 63
  • [47] EFFECT OF H2S ON DEPASSIVATION PH OF HIGH ALLOYS
    DENPO, K
    MIYASAKA, A
    OGAWA, H
    TRANSACTIONS OF THE IRON AND STEEL INSTITUTE OF JAPAN, 1986, 26 (01) : B28 - B28
  • [48] EFFECT OF H2S ON DEPASSIVATION PH OF HIGH ALLOYS
    DENPO, K
    TETSU TO HAGANE-JOURNAL OF THE IRON AND STEEL INSTITUTE OF JAPAN, 1985, 71 : 1324 - 1324
  • [49] FUEL 254-Activation of molecular hydrogen on palladium separation membrane surfaces in the presence of H2S
    Miller, James B.
    Alfonso, Dominic R.
    Howard, Bret H.
    O'Brien, Casey P.
    Morreale, Bryan D.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 235
  • [50] Effect of Cold Deformation on the Microstructures, Mechanical Properties and Corrosion Behavior of IF Steel in Simulated H2S Solutions
    Shen, Wenzhu
    Wang, Gangqiang
    Chen, Long
    Xu, Xi
    Yang, Bo
    Li, Chunfu
    ADVANCES IN ENERGY AND ENVIRONMENTAL MATERIALS, 2018, : 429 - 436
12345