Effect of temperature on the corrosion of Cu-Pd hydrogen separation membrane alloys in simulated syngas containing H2S

被引：8

作者：

Nielsen, Benjamin C. ^{[1
,2
]}

Dogan, Omer N. ^{[1
]}

Howard, Bret H. ^{[3
]}

机构：

[1] US DOE, Natl Energy Technol Lab, Albany, OR 97321 USA

[2] URS Corp, Albany, OR 97321 USA

[3] US DOE, Natl Energy Technol Lab, Pittsburgh, PA 15236 USA

来源：

CORROSION SCIENCE | 2015年 / 96卷

关键词：

Alloy; Copper; SEM; XRD; High temperature corrosion; Sulfidation; SURFACE SEGREGATION; SULFIDE; PERMEANCE;

D O I：

10.1016/j.corsci.2015.03.017

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The resistance to sulfidation of hydrogen separation membranes was examined by exposing Pd, Cu, and four Cu-Pd alloys to simulated syngas containing H2S at four different temperatures. The mass change of the samples was determined and the exposed surfaces were characterized by SEM/EDS and XRD. The binary alloys showed much better corrosion resistance than the pure metals at all temperatures. The binary alloys showed a trend reversal, with the high Pd alloys gaining the most mass at the lower temperatures due to sulfidation, while the high Cu alloys gained the most mass at the higher temperatures due to oxidation. Published by Elsevier Ltd.

引用

页码：74 / 86

页数：13

共 50 条

[11] Effect of H2S on hydrogen permeation of Pd60Cu40/V-15Ni composite membrane
Yang, J.Y.
Nishimura, C.
Komaki, M.
Journal of Alloys and Compounds, 2007, 446-447 : 575 - 578
[12] Preparation of composite membrane against H2S poisoning for hydrogen separation
Gwak, Jihye
Ayral, Andr
Komaki, Masao
Nishimura, Chikashi
Transactions of the Materials Research Society of Japan, Vol 30, No 4, 2005, 30 (04): : 991 - 993
[13] COLL 504-The influence of H2S on surface segregation patterns in a polycrystalline Pd70Cu30 hydrogen separation membrane
Miller, James B.
Matranga, Christopher
Morreale, Bryan D.
Gellman, Andrew J.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 234
[14] The effect of CO, H2S and H2O on the hydrogen permeance of Pd-Cu alloy membranes
Cugini, A
Howard, BH
Morreale, BD
Iyoha, O
Enick, RE
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U1703 - U1703
[15] H2S corrosion at low temperature
不详
MATERIALS PERFORMANCE, 2006, 45 (12) : 62 - 62
[16] High temperature corrosion behavior of alloys in reducing HCl and H2S containing environments: Thermodynamical and experimental assessment
Nimmervoll, Manuela
Mori, Gregor
Bucher, Edith
Honig, Stefan
Haubner, Roland
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2022, 73 (12): : 1979 - 2003
[17] High-temperature corrosion of austenitic alloys in HCl and H2S containing atmospheres under reducing conditions
Nimmervoll, Manuela
Mori, Gregor
Hoenig, Stefan
Haubner, Roland
CORROSION SCIENCE, 2022, 200
[18] Effect of H2S on High Temperature Corrosion of Fe–Ni–Cr Alloys in Carburizing/Oxidizing Environments
Hao Li
Weixing Chen
Oxidation of Metals, 2012, 77 : 107 - 127
[19] CORROSION-RESISTANCE OF HIGH NI-ALLOYS IN HIGH-TEMPERATURE CHLORIDE SOLUTIONS CONTAINING H2S
MASAMURA, K
ISHIZAWA, Y
INAZUMI, T
HASHIZUME, S
MATSUSHIMA, I
TETSU TO HAGANE-JOURNAL OF THE IRON AND STEEL INSTITUTE OF JAPAN, 1988, 74 (06): : 1081 - 1088
[20] Effect of High Temperature on the Aqueous H2S Corrosion of Mild Steel
Gao, Shujun
Jin, Peng
Brown, Bruce
Young, David
Nesic, Srdjan
Singer, Marc
CORROSION, 2017, 73 (10) : 1188 - 1191

← 1 2 3 4 5 →