Cyclic Alternating Ring-Opening Metathesis Polymerization (CAROMP). Rapid Access to Functionalized Cyclic Polymers

被引：28
|
作者：
Song, Airong [1 ]
Parker, Kathlyn A. [1 ]
Sampson, Nicole S. [1 ]
机构：
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 17期
关键词：
CLICK CYCLIZATION; DRUG-DELIVERY; ARCHITECTURE; CATALYST; EFFICIENT; CANCER; ROUTE;
D O I：
10.1021/ol101432m
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Catalysis of alternating ROMP with (H(2)IMes)Cl2Ru=CHPh(OiPr), the second generation Hoveyda Grubbs catalyst, provided an entirely cyclic alternating polymer. Conditions for the cyclic AROMP were used to prepare a polymer in which one of the repeat units bore a primary alkyl chloride that was used for further elaboration.
引用
收藏
页码：3729 / 3731
页数：3
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