Cyclic Alternating Ring-Opening Metathesis Polymerization (CAROMP). Rapid Access to Functionalized Cyclic Polymers

被引：28
|
作者：
Song, Airong [1 ]
Parker, Kathlyn A. [1 ]
Sampson, Nicole S. [1 ]
机构：
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 17期
关键词：
CLICK CYCLIZATION; DRUG-DELIVERY; ARCHITECTURE; CATALYST; EFFICIENT; CANCER; ROUTE;
D O I：
10.1021/ol101432m
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Catalysis of alternating ROMP with (H(2)IMes)Cl2Ru=CHPh(OiPr), the second generation Hoveyda Grubbs catalyst, provided an entirely cyclic alternating polymer. Conditions for the cyclic AROMP were used to prepare a polymer in which one of the repeat units bore a primary alkyl chloride that was used for further elaboration.
引用
收藏
页码：3729 / 3731
页数：3
相关论文
共 50 条
  • [21] Ring-Opening Metathesis Polymerization to Access Degradable Imine-Based Polymers
    Li, Wu
    Cheng, Si-Jia
    Li, You-Gui
    Khan, Muhammad Asadullah
    Chen, Min
    CHINESE JOURNAL OF POLYMER SCIENCE, 2024,
  • [22] Alternating Radical Ring-Opening Polymerization of Cyclic Ketene Acetals: Access to Tunable and Functional Polyester Copolymers
    Hill, Megan R.
    Kubo, Tomohiro
    Goodrich, Sofia L.
    Figg, C. Adrian
    Sumerlin, Brent S.
    MACROMOLECULES, 2018, 51 (14) : 5079 - 5084
  • [23] Ring-opening polymerization of cyclic hemiacetal esters for the preparation of degradable polymers
    Hillmyer, Marc
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [24] The Ring-Opening Polymerization-Polycondensation (ROPPOC) Approach to Cyclic Polymers
    Kricheldorf, Hans R.
    Weidner, Steffen M.
    MACROMOLECULAR RAPID COMMUNICATIONS, 2020, 41 (14)
  • [25] Thermoresponsive polymers based on ring-opening metathesis polymerization
    Zhao, Yuming
    Zhang, Ke
    POLYMER CHEMISTRY, 2016, 7 (24) : 4081 - 4089
  • [26] Metallosupramolecular polymers via ring-opening metathesis polymerization
    Elacqua, Elizabeth
    Weck, Marcus
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [27] Synthesis of Bottlebrush Polymers by Ring-Opening Metathesis Polymerization
    Chen, Kerui
    Hu, Xin
    Qiu, Jiangkai
    Zhu, Ning
    Guo, Kai
    PROGRESS IN CHEMISTRY, 2020, 32 (01) : 93 - 102
  • [28] Synthesis of High Performance Cyclic Olefin Polymers (COPs) with Ester Group via Ring-Opening Metathesis Polymerization
    Cui, Jing
    Yang, Ji-Xing
    Li, Yan-Guo
    Li, Yue-Sheng
    POLYMERS, 2015, 7 (08): : 1389 - 1409
  • [29] RING-OPENING ISOMERIZATION POLYMERIZATION OF CYCLIC IMINOCARBONATES
    MIYAMOTO, M
    AOI, K
    MORIMOTO, M
    CHUJO, Y
    SAEGUSA, T
    MACROMOLECULES, 1992, 25 (22) : 5878 - 5885
  • [30] Telechelics Based on Catalytic Alternating Ring-Opening Metathesis Polymerization
    Pal, Subhajit
    Alizadeh, Mahshid
    Kilbinger, Andreas F. M.
    ACS MACRO LETTERS, 2019, 8 (10) : 1396 - 1401
12345