Metal-catalyzed additions of H-P(O) bonds to carbon-carbon unsaturated bonds

被引：139

作者：

Xu, Qing ^{[2
]}

Han, Li-Biao ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

[2] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 01期

关键词：

Organophosphorus compounds; Transition metal catalysts; Regio- and stereoselective addition; H-P(O) bonds; Carbon-carbon unsaturated bonds; ACTIVE PHOSPHINE OXIDES; OXIDATIVE ADDITION; HECK REACTION; P-H; ASYMMETRIC HYDROSILYLATION; MARKOVNIKOV ADDITION; PHOSPHORUS-COMPOUNDS; POLYDENTATE LIGANDS; SELECTIVE FORMATION; TERMINAL ALKYNES;

D O I：

10.1016/j.jorganchem.2010.08.043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this short review, we briefly summarize our studies on metal-catalyzed additions of H-P(O) bonds to carbon-carbon unsaturated compounds (alkynes, alkenes, allenes, dienes and related). These new reactions provide regio- and stereoselective ways for the preparation of a variety of organophosphorus compounds. Mechanistic aspects related to the catalytic processes are discussed. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：130 / 140

页数：11

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