Metal-catalyzed additions of H-P(O) bonds to carbon-carbon unsaturated bonds

被引：139
|
作者：
Xu, Qing [2 ]
Han, Li-Biao [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan
[2] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 01期
关键词：
Organophosphorus compounds; Transition metal catalysts; Regio- and stereoselective addition; H-P(O) bonds; Carbon-carbon unsaturated bonds; ACTIVE PHOSPHINE OXIDES; OXIDATIVE ADDITION; HECK REACTION; P-H; ASYMMETRIC HYDROSILYLATION; MARKOVNIKOV ADDITION; PHOSPHORUS-COMPOUNDS; POLYDENTATE LIGANDS; SELECTIVE FORMATION; TERMINAL ALKYNES;
D O I：
10.1016/j.jorganchem.2010.08.043
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this short review, we briefly summarize our studies on metal-catalyzed additions of H-P(O) bonds to carbon-carbon unsaturated compounds (alkynes, alkenes, allenes, dienes and related). These new reactions provide regio- and stereoselective ways for the preparation of a variety of organophosphorus compounds. Mechanistic aspects related to the catalytic processes are discussed. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：130 / 140
页数：11
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