Delocalized mixed-valence Bi- and trinuclear complexes with short Cu-Cu bonds

被引：24
|
作者：
Yang, Lei
Powell, Douglas R.
Klein, Eric L.
Grohmann, Andreas
Houser, Robert P.
机构：
[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA
[2] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 17期
关键词：
D O I：
10.1021/ic7010474
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two mixed-valence copper complexes were synthesized with ligands N-(2-pyridylmethyl)acetamide (Hpmac) and N,N'-(2-methyl2-pyridylpropan-1,3-diyl)bis(acetamide) (H2pp(ac)(2)). Dimer [CU2(pmac)(2)]OTf and trimer [CU3(pp(ac)(2))(2)]center dot NaOTf both contain fully delocalized, mixed-valence (CuCu1.5)-Cu-1.5 moieties.
引用
收藏
页码：6831 / 6833
页数：3
相关论文
共 50 条
  • [41] Cu3 + PROBLEM IN MIXED-VALENCE COPPER OXIDE SUPERCONDUCTORS.
    Bertaut, E.F.
    Chemica scripta, 1987, 28 (01):
  • [42] THE CU-3+ PROBLEM IN MIXED-VALENCE COPPER-OXIDE SUPERCONDUCTORS
    BERTAUT, EF
    CHEMICA SCRIPTA, 1988, 28 (01): : 57 - 57
  • [43] Mixed-mode interface toughness of wafer-level Cu-Cu bonds using asymmetric chevron test
    Tadepalli, Rajappa
    Turner, Kevin T.
    Thompson, Carl V.
    JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 2008, 56 (03) : 707 - 718
  • [44] STRONGLY CORRELATED ELECTRONS IN MIXED-VALENCE CONDUCTORS DCNQI-CU SALTS
    SUZUMURA, Y
    ONO, Y
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1993, 62 (09) : 3244 - 3256
  • [45] Cu(I)Cu(II)BTC, a microporous mixed-valence MOF via reduction of HKUST-1
    Ahmed, Adham
    Robertson, Craig M.
    Steiner, Alexander
    Whittles, Thomas
    Ho, Alexandra
    Dhanak, Vinod
    Zhang, Haifei
    RSC ADVANCES, 2016, 6 (11): : 8902 - 8905
  • [46] Low temperature Cu-Cu bonding by transient liquid phase sintering of mixed Cu nanoparticles and Sn-Bi eutectic powders
    Faiz, M. Khairi
    Bansho, Kazuma
    Suga, Tadatomo
    Miyashita, Tomoyuki
    Yoshida, Makoto
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (21) : 16433 - 16443
  • [47] Observation of the order of Cu ions in the mixed-valence state of (DMe-DCNQI)(2)Cu by Raman scattering
    Sekine, T
    Kamioka, T
    Kawano, R
    Tsutsumi, K
    Tanokura, Y
    Aonuma, S
    Sawa, H
    Kato, R
    SYNTHETIC METALS, 1997, 86 (1-3) : 2071 - 2072
  • [48] Cu(I)/Cu(II) Creutz-Taube Mixed-Valence 2D Coordination Polymers
    Li, Ning
    Wu, Gang
    Xi, Shibo
    Wei, Fengxia
    Lin, Ming
    Qiu, Jinjun
    Zheng, Jin-Cheng
    Yi, Jiabao
    Seng, Debbie Hwee Leng
    Lee, Coryl Jing Jun
    Repaka, D. V. Maheswar
    Liu, Xiaoming
    Wong, Zicong Marvin
    Zhu, Qiang
    Yang, Shuo-Wang
    Luo, He-Kuan
    SMALL METHODS, 2023, 7 (01)
  • [49] Construction of mixed-valence Cu(I)/Cu(II) 3-D framework and its photocatalytic activities
    Xu, Zhouqing
    Li, Qingqing
    He, Xinglei
    Li, Huijun
    Wang, Yuan
    Cao, Jianliang
    POLYHEDRON, 2018, 151 : 478 - 482
  • [50] Structural and magnetic studies on a new mixed-valence Cu(I)-Cu(II) octanuclear cluster with a dithiocarbarnate derivative
    Kawajiri, Ryo
    Okubo, Takashi
    Mitani, Tadaoki
    POLYHEDRON, 2006, 25 (13) : 2650 - 2654
12345