Delocalized mixed-valence Bi- and trinuclear complexes with short Cu-Cu bonds

被引：24
|
作者：
Yang, Lei
Powell, Douglas R.
Klein, Eric L.
Grohmann, Andreas
Houser, Robert P.
机构：
[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA
[2] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 17期
关键词：
D O I：
10.1021/ic7010474
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two mixed-valence copper complexes were synthesized with ligands N-(2-pyridylmethyl)acetamide (Hpmac) and N,N'-(2-methyl2-pyridylpropan-1,3-diyl)bis(acetamide) (H2pp(ac)(2)). Dimer [CU2(pmac)(2)]OTf and trimer [CU3(pp(ac)(2))(2)]center dot NaOTf both contain fully delocalized, mixed-valence (CuCu1.5)-Cu-1.5 moieties.
引用
收藏
页码：6831 / 6833
页数：3
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