Delocalized mixed-valence Bi- and trinuclear complexes with short Cu-Cu bonds

被引：24

作者：

Yang, Lei

Powell, Douglas R.

Klein, Eric L.

Grohmann, Andreas

Houser, Robert P.

机构：

[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA

[2] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 17期

关键词：

D O I：

10.1021/ic7010474

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two mixed-valence copper complexes were synthesized with ligands N-(2-pyridylmethyl)acetamide (Hpmac) and N,N'-(2-methyl2-pyridylpropan-1,3-diyl)bis(acetamide) (H2pp(ac)(2)). Dimer [CU2(pmac)(2)]OTf and trimer [CU3(pp(ac)(2))(2)]center dot NaOTf both contain fully delocalized, mixed-valence (CuCu1.5)-Cu-1.5 moieties.

引用

页码：6831 / 6833

页数：3

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