Partial oxidation of methane in a catalytic ruthenium membrane reactor

被引:8
|
作者
Paturzo, L
Gallucci, F
Basile, A
Pertici, P
Scalera, N
Vitulli, G
机构
[1] Univ Calabria, Inst Membrane Technol, ITM, CNRS, I-87030 Arcavacata Di Rende, CS, Italy
[2] Univ Pisa, ICCOM, CNR, Sez Pisa,Dipartimento Chim & Chim Ind, I-50126 Pisa, Italy
关键词
D O I
10.1021/ie020873x
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A catalytic ruthenium membrane reactor (CRMR) is analyzed with regard to the methane partial oxidation reaction for synthesis gas production. The catalytic membrane consists of a commercial ceramic tube, where two different layers of ruthenium nanoparticles have been deposited on the inner surface. The metal deposition was performed by decomposition of a Ru complex under mild conditions. Different operating modes are analyzed for CRMR to establish the potentiality of the Ru catalyst deposited on the tubular ceramic support. A comparison in terms of methane conversion at various temperatures is presented. Experimental runs of CRMR containing a one-Ru-layer membrane and a two-Ru-layer membrane have also been compared.
引用
收藏
页码:2968 / 2974
页数:7
相关论文
共 50 条
  • [41] CATALYTIC STUDIES OF METHANE PARTIAL OXIDATION
    WALKER, GS
    LAPSZEWICZ, JA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 54 - CATL
  • [42] Catalytic partial oxidation of methane to formaldehyde
    de Vekki, A. V.
    Marakaev, S. T.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2009, 82 (04) : 521 - 536
  • [43] Microreactor for the Catalytic Partial Oxidation of Methane
    Widodo Wahyu Puwanto
    Yuswan Muharam
    Journal of Natural Gas Chemistry, 2006, (04) : 271 - 274
  • [44] CATALYTIC REACTIONS OF PARTIAL METHANE OXIDATION
    KRYLOV, OV
    CATALYSIS TODAY, 1993, 18 (03) : 209 - 302
  • [45] Catalytic partial oxidation of methane to syngas: review of perovskite catalysts and membrane reactors
    Elbadawi, Abdalwadood H.
    Ge, Lei
    Li, Zhiheng
    Liu, Shaomin
    Wang, Shaobin
    Zhu, Zhonghua
    CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2021, 63 (01): : 1 - 67
  • [46] Catalytic partial oxidation of methane in a high-temperature reverse-flow reactor
    Neumann, D
    Veser, G
    AICHE JOURNAL, 2005, 51 (01) : 210 - 223
  • [47] Vanadium pentoxide catalytic membrane reactor for partial oxidation of 1-butene
    Moon, S
    Kim, T
    Park, S
    Jung, J
    Hong, S
    3RD WORLD CONGRESS ON OXIDATION CATALYSIS, 1997, 110 : 1231 - 1238
  • [48] CATALYTIC OXIDATION OF METHANE IN A SINGLE GRAIN REACTOR
    HUSZAR, K
    RACZ, G
    SZEKELY, G
    KEMIAI KOZLEMENYEK, 1971, 35 (01): : 21 - &
  • [49] MATHEMATICAL MODEL OF A REACTOR FOR PARTIAL OXIDATION OF METHANE
    GAUTIER, M
    LEVASSEU.J
    CHEMIE INGENIEUR TECHNIK, 1968, 40 (14) : 726 - &
  • [50] Simulations of the effect of hydrodynamic conditions and properties of membranes on the catalytic performance of a fluidized-bed membrane reactor for partial oxidation of methane
    Ostrowski, T
    Mleczko, L
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1999, 77 (02): : 363 - 369