Partial oxidation of methane in a catalytic ruthenium membrane reactor

被引：8
|
作者：
Paturzo, L
Gallucci, F
Basile, A
Pertici, P
Scalera, N
Vitulli, G
机构：
[1] Univ Calabria, Inst Membrane Technol, ITM, CNRS, I-87030 Arcavacata Di Rende, CS, Italy
[2] Univ Pisa, ICCOM, CNR, Sez Pisa,Dipartimento Chim & Chim Ind, I-50126 Pisa, Italy
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2003年 / 42卷 / 13期
关键词：
D O I：
10.1021/ie020873x
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A catalytic ruthenium membrane reactor (CRMR) is analyzed with regard to the methane partial oxidation reaction for synthesis gas production. The catalytic membrane consists of a commercial ceramic tube, where two different layers of ruthenium nanoparticles have been deposited on the inner surface. The metal deposition was performed by decomposition of a Ru complex under mild conditions. Different operating modes are analyzed for CRMR to establish the potentiality of the Ru catalyst deposited on the tubular ceramic support. A comparison in terms of methane conversion at various temperatures is presented. Experimental runs of CRMR containing a one-Ru-layer membrane and a two-Ru-layer membrane have also been compared.
引用
收藏
页码：2968 / 2974
页数：7
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