Reactions of 2-substituted epichlorohydrins

被引：4
|
作者：
Tanyeli, C
Demir, AS
Akhmedov, IM
Ozgul, E
Kandemir, CG
机构：
[1] Department of Chemistry, Middle East Technical University
来源：
SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 16期
关键词：
Cyanides;
D O I：
10.1080/00397919608004600
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
2-Substituted epichlorohydrins have been synthesized by starting with 1,2-dichloro acetone and various alkyl and aryl halides via dichlorohydrins followed by cyclization. The reactive 2-substituted epichlorohydrins were subjected to nucleophilic attacking of azide and cyanide ions to afford corresponding beta-azido alcohols and alpha,beta-unsaturated nitriles.
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页码：2967 / 2980
页数：14
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