Reactions of 2-substituted epichlorohydrins

被引:4
|
作者
Tanyeli, C
Demir, AS
Akhmedov, IM
Ozgul, E
Kandemir, CG
机构
[1] Department of Chemistry, Middle East Technical University
关键词
Cyanides;
D O I
10.1080/00397919608004600
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
2-Substituted epichlorohydrins have been synthesized by starting with 1,2-dichloro acetone and various alkyl and aryl halides via dichlorohydrins followed by cyclization. The reactive 2-substituted epichlorohydrins were subjected to nucleophilic attacking of azide and cyanide ions to afford corresponding beta-azido alcohols and alpha,beta-unsaturated nitriles.
引用
收藏
页码:2967 / 2980
页数:14
相关论文
共 50 条
  • [21] Solvent and structural effects on the kinetics of the reactions of 2-substituted cyclohex-1-enylcarboxylic and 2-substituted benzoic acids with diazodiphenyl with diazodiphenylmethane
    Nikolic, J. B.
    Uscumlic, G. S.
    Juranic, I. O.
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2007, 39 (12) : 664 - 671
  • [22] Chirogenic [3 + 2]-photocycloaddition reactions of 2-substituted naphthoquinones with cyclic alkenes
    Christiane Müller
    Andreas Bauer
    Thorsten Bach
    Photochemical & Photobiological Sciences, 2011, 10 : 1463 - 1468
  • [23] 2-SUBSTITUTED NONAFLUORODIPHENYLS
    FENTON, DE
    PARK, AJ
    SHAW, D
    MASSEY, AG
    TETRAHEDRON LETTERS, 1964, (15-6) : 949 - 950
  • [24] 2-substituted imidazoles
    Kano, N
    Murai, T
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1998, 56 (12) : 1087 - 1089
  • [25] 2-SUBSTITUTED HISTAMINES
    DZIURON, P
    SCHUNACK, W
    ARCHIV DER PHARMAZIE, 1974, 307 (02) : 89 - 95
  • [26] 2-SUBSTITUTED OCTAHYDROPHENANTHRIDINES
    BINDRA, JS
    ANAND, N
    INDIAN JOURNAL OF CHEMISTRY, 1967, 5 (07): : 344 - &
  • [27] REACTIONS OF 3-METHYLBENZYNE WITH 2-SUBSTITUTED FURANS - STERIC EFFECTS
    NEWMAN, MS
    KANNAN, R
    JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (21): : 3356 - 3359
  • [28] Synthesis and reactions of 2-substituted ethyl N-alkylmalonylhydroxamic acids
    Hoffman, RV
    Madan, S
    JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (12): : 4876 - 4885
  • [29] Reactions of 2-Substituted Pyridines with Titanocenes and Zirconocenes: Coupling versus Dearomatisation
    Reiss, Fabian
    Altenburger, Kai
    Becker, Lisanne
    Schubert, Kathleen
    Jiao, Haijun
    Spannenberg, Anke
    Hollmann, Dirk
    Arndt, Perdita
    Rosenthal, Uwe
    CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (10) : 3361 - 3369
  • [30] The kinetics of the reactions of 2-substituted nicotinic acids with diazodiphenylmethane in various alcohols
    Drmanic, SZ
    Jovanovic, BZ
    Marinkovic, AD
    Misic-Vukovic, MM
    JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2003, 68 (07) : 515 - 524