Switchable Open-Cage Fullerene for Water Encapsulation

被引：58

作者：

Zhang, Qianyan ^{[2
]}

Pankewitz, Tobias ^{[3
]}

Liu, Shuming ^{[2
]}

Klopper, Wim ^{[1
,3
]}

Gan, Liangbing ^{[2
,4
]}

机构：

[1] Karlsruher Inst Technol, Ctr Funct Nanostruct, D-76049 Karlsruhe, Germany

[2] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100080, Peoples R China

[3] Karlsruher Inst Technol, Inst Phys Chem, Abt Theoret Chem, D-76049 Karlsruhe, Germany

[4] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 51期

关键词：

density functional calculations; fullerenes; molecular devices; supramolecular chemistry; BASIS-SETS; MOLECULAR-HYDROGEN; ORIFICE; HELIUM; C-60; ENERGIES;

D O I：

10.1002/anie.201004879

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A molecular container for a single water molecule was obtained by chemical transformation of a [60]fullerene cage. A phosphate moiety acts as an effective "stopper" in the orifice (see picture). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9935 / 9938

页数：4

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