Switchable Open-Cage Fullerene for Water Encapsulation

被引：58
|
作者：
Zhang, Qianyan [2 ]
Pankewitz, Tobias [3 ]
Liu, Shuming [2 ]
Klopper, Wim [1 ,3 ]
Gan, Liangbing [2 ,4 ]
机构：
[1] Karlsruher Inst Technol, Ctr Funct Nanostruct, D-76049 Karlsruhe, Germany
[2] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100080, Peoples R China
[3] Karlsruher Inst Technol, Inst Phys Chem, Abt Theoret Chem, D-76049 Karlsruhe, Germany
[4] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 51期
关键词：
density functional calculations; fullerenes; molecular devices; supramolecular chemistry; BASIS-SETS; MOLECULAR-HYDROGEN; ORIFICE; HELIUM; C-60; ENERGIES;
D O I：
10.1002/anie.201004879
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A molecular container for a single water molecule was obtained by chemical transformation of a [60]fullerene cage. A phosphate moiety acts as an effective "stopper" in the orifice (see picture). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：9935 / 9938
页数：4
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