Switchable Open-Cage Fullerene for Water Encapsulation

被引：58
|
作者：
Zhang, Qianyan [2 ]
Pankewitz, Tobias [3 ]
Liu, Shuming [2 ]
Klopper, Wim [1 ,3 ]
Gan, Liangbing [2 ,4 ]
机构：
[1] Karlsruher Inst Technol, Ctr Funct Nanostruct, D-76049 Karlsruhe, Germany
[2] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100080, Peoples R China
[3] Karlsruher Inst Technol, Inst Phys Chem, Abt Theoret Chem, D-76049 Karlsruhe, Germany
[4] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 51期
关键词：
density functional calculations; fullerenes; molecular devices; supramolecular chemistry; BASIS-SETS; MOLECULAR-HYDROGEN; ORIFICE; HELIUM; C-60; ENERGIES;
D O I：
10.1002/anie.201004879
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A molecular container for a single water molecule was obtained by chemical transformation of a [60]fullerene cage. A phosphate moiety acts as an effective "stopper" in the orifice (see picture). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：9935 / 9938
页数：4
相关论文
共 50 条
  • [1] Encapsulation of Formaldehyde and Hydrogen Cyanide in an Open-Cage Fullerene
    Chen, Chi-Shian
    Kuo, Ting-Shen
    Yeh, Wen-Yann
    CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (26) : 8773 - 8776
  • [2] Open-cage fullerene derivatives suitable for the encapsulation of a hydrogen molecule
    Iwamatsu, S
    Murata, S
    Andoh, Y
    Minoura, M
    Kobayashi, K
    Mizorogi, N
    Nagase, S
    JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (12): : 4820 - 4825
  • [3] Synthesis of open-cage fullerene derivatives and encapsulation of small molecules
    Komatsu, K
    Murata, Y
    Murata, M
    FULLERENES AND NANOTUBES: THE BUILDING BLOCKS OF NEXT GENERATION NANODEVICES, 2003, 2003 (15): : 252 - 257
  • [4] Methane in an Open-Cage [60]Fullerene
    Whitener, Keith E., Jr.
    Cross, R. James
    Saunders, Martin
    Iwamatsu, Sho-ichi
    Murata, Shizuaki
    Mizorogi, Naomi
    Nagase, Shigeru
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (18) : 6338 - +
  • [5] Carbon monoxide inside an open-cage fullerene
    Iwamatsu, Sho-ichi
    Stanisky, Christopher M.
    Cross, R. James
    Saunders, Martin
    Mizorogi, Naomi
    Nagase, Shigeru
    Murata, Shizuaki
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (32) : 5337 - 5340
  • [6] Recognition of hydrogen isotopomers by an open-cage fullerene
    Murata, Yasujiro
    Chuang, Shih-Ching
    Tanabe, Fumiyuki
    Murata, Michihisa
    Komatsu, Koichi
    PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2013, 371 (1998):
  • [7] Open-cage fullerenes: Synthesis, structure, and molecular encapsulation
    Iwamatsu, S
    Murata, S
    SYNLETT, 2005, (14) : 2117 - 2129
  • [8] Floating single hydrogen molecule in an open-cage fullerene
    Sawa, H
    Wakabayashi, Y
    Murata, Y
    Murata, M
    Komatsu, K
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (13) : 1981 - 1983
  • [9] Open-cage fullerene with a stopper acts as a molecular vial for a single water molecule
    Xu, Liang
    Liang, Sisi
    Sun, Jiahao
    Gan, Liangbing
    Organic Chemistry Frontiers, 2015, 2 (11): : 1500 - 1504
  • [10] Synthesis of Metal Complexes with an Open-Cage Fullerene as the Ligand
    Zhou, Zishuo
    Xin, Nana
    Gan, Liangbing
    CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (02) : 451 - 457
12345