Rhodium-Catalyzed Dehydrogenative Annulation of N-Arylmethanimines with Vinylene Carbonate for Synthesizing Quinolines

被引：44

作者：

Hu, Yan ^{[1
]}

Nan, Jiang ^{[1
]}

Yin, Jiacheng ^{[1
]}

Huang, Guanjie ^{[1
]}

Ren, Xin ^{[1
]}

Ma, Yangmin ^{[1
]}

机构：

[1] Shaanxi Univ Sci & Technol, Coll Chem & Chem Engn, Shaanxi Key Lab Chem Addit Ind, Xian 710021, Peoples R China

来源：

ORGANIC LETTERS | 2021年 / 23卷 / 21期

关键词：

QUINAZOLINE; CYCLIZATION; COMPLEXES; ALCOHOLS; KETONES;

D O I：

10.1021/acs.orglett.1c03231

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Here we report a novel Rh-catalyzed C-H/C-H alkenylation of N-arylmethanimines with vinylene carbonate acting as a vinylene unit. Forty examples of C3,C4-nonsubstituted quinolines were achieved from commercially available starting materials. This identified process features an exceedingly simple system, a lower loading of catalyst, and the capacity for postfunctionalization with bioactive molecules.

引用

页码：8527 / 8532

页数：6

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