Growth behavior of anodic oxide formed by aluminum anodizing in glutaric and its derivative acid electrolytes

被引:32
|
作者
Nakajima, Daiki [1 ]
Kikuchi, Tatsuya [1 ]
Natsui, Shungo [1 ]
Suzuki, Ryosuke O. [1 ]
机构
[1] Hokkaido Univ, Fac Engn, Kita Ku, Sapporo, Hokkaido 0608628, Japan
基金
日本学术振兴会;
关键词
Aluminum; Anodizing; Glutaric acid; Ketoglutaric acid; Acetonedicarboxylic acid; ORDERED POROUS ALUMINA; NANOPOROUS ALUMINA; OXALIC-ACID; FABRICATION; ANODIZATION; ARRAYS; FILMS; NANOSTRUCTURES; MEMBRANES;
D O I
10.1016/j.apsusc.2014.10.014
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The growth behavior of anodic oxide films formed via anodizing in glutaric and its derivative acid solutions was investigated based on the acid dissociation constants of electrolytes. High-purity aluminum foils were anodized in glutaric, ketoglutaric, and acetonedicarboxylic acid solutions under various electrochemical conditions. A thin barrier anodic oxide film grew uniformly on the aluminum substrate by glutaric acid anodizing, and further anodizing caused the film to breakdown due to a high electric field. In contrast, an anodic porous alumina film with a submicrometer-scale cell diameter was successfully formed by ketoglutaric acid anodizing at 293 K. However, the increase and decrease in the temperature of the ketoglutaric acid resulted in non-uniform oxide growth and localized pitting corrosion of the aluminum substrate. An anodic porous alumina film could also be fabricated by acetonedicarboxylic acid anodizing due to the relatively low dissociation constants associated with the acid. Acid dissociation constants are an important factor for the fabrication of anodic porous alumina films. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:364 / 370
页数:7
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