Oxosulfido complexes of platinum -: (Ph3P)2Pt(S2O) and (Ph3P)4Pt2(μ-S)(μ-SO) -: Their formation and properties

被引：31

作者：

Ishii, A

Murata, M

Oshida, H

Matsumoto, K

Nakayama, J

机构：

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 20期

关键词：

platinum; S ligands; oxo ligands; SULFUR-CONTAINING LIGANDS; RAY-STRUCTURE-ANALYSIS; DISULFUR MONOXIDE; METAL-COMPLEXES; OXIDATIVE ADDITION; VIC-DISULFOXIDE; S-OXIDE; CHEMISTRY; THIOSULFINATO; DIOXIDE;

D O I：

10.1002/ejic.200300348

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The platinum S2O complex [(Ph3P)(2)Pt(S2O)] (10) was obtained by S2O transfer reactions from tetrathiolane 2-oxide (8), tetrathiolane 2,3-dioxide (5), and pentathiane 3-oxide (6) to [(C2H4)Pt(PPh3)(2)] (4). The S20 complex 10 further reacts with 4 to give a novel binuclear platinum complex 16, which is found to be a source of several platinum SnOm complexes. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

引用

页码：3716 / 3721

页数：6

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