Oxosulfido complexes of platinum -: (Ph3P)2Pt(S2O) and (Ph3P)4Pt2(μ-S)(μ-SO) -: Their formation and properties

被引：31
|
作者：
Ishii, A
Murata, M
Oshida, H
Matsumoto, K
Nakayama, J
机构：
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 20期
关键词：
platinum; S ligands; oxo ligands; SULFUR-CONTAINING LIGANDS; RAY-STRUCTURE-ANALYSIS; DISULFUR MONOXIDE; METAL-COMPLEXES; OXIDATIVE ADDITION; VIC-DISULFOXIDE; S-OXIDE; CHEMISTRY; THIOSULFINATO; DIOXIDE;
D O I：
10.1002/ejic.200300348
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The platinum S2O complex [(Ph3P)(2)Pt(S2O)] (10) was obtained by S2O transfer reactions from tetrathiolane 2-oxide (8), tetrathiolane 2,3-dioxide (5), and pentathiane 3-oxide (6) to [(C2H4)Pt(PPh3)(2)] (4). The S20 complex 10 further reacts with 4 to give a novel binuclear platinum complex 16, which is found to be a source of several platinum SnOm complexes. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).
引用
收藏
页码：3716 / 3721
页数：6
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