Transition-Metal-Catalyzed Carboxylation of C-H Bonds

被引：170
|
作者：
Ackermann, Lutz [1 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 17期
关键词：
C-H activation; carbon dioxide; copper; homogeneous catalysis; gold; CARBENE COPPER(I) COMPLEXES; CARBON-DIOXIDE; ORGANOZINC REAGENTS; ARENES; CO2; HETEROCYCLES;
D O I：
10.1002/anie.201007883
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
CO2 in a fix: Gold and copper complexes of N-heterocyclic carbenes recently enabled efficient direct carboxylation of (hetero)arenes having moderately acidic C-H bonds under remarkably mild reaction conditions (IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：3842 / 3844
页数：3
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