Transition-Metal-Catalyzed C-H Alkynylation

被引：18

作者：

Wang, Mingming ^{[1
]}

Wang, Zixiao ^{[2
]}

Shang, Ming ^{[1
]}

Dai, Huixiong ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

[2] Shanghai Univ, Dept Chem, Innovat Drug Res Ctr, Shanghai 200444, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 35卷 / 03期

基金：

中国国家自然科学基金;

关键词：

alkynylation; C-H activation; alkyne; cross dehydrogen coupling; GACL3-CATALYZED ORTHO-ETHYNYLATION; TERMINAL ALKYNES; ARENES; COPPER; BONDS; GOLD; HETEROCYCLES; INDOLES; AZOLES;

D O I：

10.6023/cjoc201412048

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkynyl compounds are paramount skeletons in pharmaceuticals and natural products, and great importance has been attached to its synthesis by organic chemists. Recently, transition-metal-catalyzed C-H alkynylation has attracted tremendous interest as a valuable tool for construction of alkynyl compounds. This review gives a summary of progress having been made in the field of the C(sp(2))-H and C(sp(3))-H alkynylation over the last ten years.

引用

页码：570 / 577

页数：8

共 43 条

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