Studies on the mechanism of chemiluminescence: Synthesis and chemiluminescent properties of the 5-hydroperoxide analogue of coelenterate luciferin

被引：8
|
作者：
Teranishi, K
Hisamatsu, M
Yamada, T
机构：
[1] Faculty of Bioresources, Mie University, Kamihama, Tsu
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 46期
关键词：
D O I：
10.1016/0040-4039(96)01927-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The 5-hydroperoxide analogue of coelenterate luciferin has been synthesized and is one of the postulated intermediates in chemiluminescent reactions of coelenterate luciferin, Cypridina luciferin, and its analogues. The 5-hydroperoxide analogue emitted weak light in chemiluminescent reactions in several solvent systems. However, it did pot generate any amide. This research leads to the conclusion that 5-hydroperoxide is not an important intermediate in chemiluminescent reactions. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码：8425 / 8428
页数：4
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