Studies on the mechanism of chemiluminescence: Synthesis and chemiluminescent properties of the 5-hydroperoxide analogue of coelenterate luciferin

被引:8
|
作者
Teranishi, K
Hisamatsu, M
Yamada, T
机构
[1] Faculty of Bioresources, Mie University, Kamihama, Tsu
关键词
D O I
10.1016/0040-4039(96)01927-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The 5-hydroperoxide analogue of coelenterate luciferin has been synthesized and is one of the postulated intermediates in chemiluminescent reactions of coelenterate luciferin, Cypridina luciferin, and its analogues. The 5-hydroperoxide analogue emitted weak light in chemiluminescent reactions in several solvent systems. However, it did pot generate any amide. This research leads to the conclusion that 5-hydroperoxide is not an important intermediate in chemiluminescent reactions. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:8425 / 8428
页数:4
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