Dipyridine[5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinato] cobalt(II) pyridine tetrasolvate monohydrate hydrate

被引:7
|
作者
Li, Zong-Sheng [1 ]
Chai, Jian-She [1 ]
机构
[1] Capital Univ Econ & Business, Coll Safety & Environm Engn, Beijing 100070, Peoples R China
关键词
D O I
10.1107/S1600536807015061
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Co(C48H28N4O8)( C5H5N) 2]center dot 4C(5)H(5)N center dot-H2O, the Co atom lies on a fourfold inversion axis, with the N atom and one C atom of the axial pyridine ligand on a twofold axis. Four pyridine solvent molecules hydrogen bond to the carboxylate groups of the porphyrin. The structure generates a hydrophobic void that incorporates a disordered solvent water molecule whose O atom lies on another fourfold inversion axis.
引用
收藏
页码:M1533 / M1535
页数:3
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