[5,10,15,20-Tetrakis(4-tolyl)porphyrin]zinc(II) dichloromethane solvate

被引：1
|
作者：
McGill, Sean [1 ]
Nesterov, Vladimir N. [2 ]
Gould, Stephanie L. [1 ]
机构：
[1] Austin Coll, Dept Chem, Sherman, TX 75090 USA
[2] Univ N Texas, Dept Chem, Denton, TX 76203 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
基金：
美国国家科学基金会;
关键词：
INCLUSION; CHEMISTRY; MODES;
D O I：
10.1107/S1600536810019963
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Zn(C48H36N4)] ·CH2Cl2, the ZnII atom lies on an inversion center and the dichloro-methane solvent molecule is disordered around an inversion center. The tolyl substituents are twisted compared to the central aromatic ring system of the porphyrin, similar to what is seen in previously published structures of this molecule [Dastidar & Goldberg (1996). Acta Cryst. C52, 1976-1980]. The dihedral angles between the mean planes of the tolyl rings and the central ring are 66.98 (6) and 60.40 (6)°.
引用
收藏
页码：M723 / U144
页数：10
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